RAS Chemistry & Material ScienceКинетика и катализ Kinetics and Catalysis

  • ISSN (Print) 0453-8811
  • ISSN (Online) 3034-5413

Features of Catalytic Pyrolysis of C−C Hydrocarbons on Nickel-tin Catalyst Obtained by Mechanochemical Alloying

PII
S3034541325040037-1
DOI
10.7868/S3034541325040037
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 66 / Issue number 4
Pages
271-280
Abstract
Catalytic pyrolysis has been considered as one of the most effective methods for processing light C hydrocarbons. In this study, a Ni−Sn catalyst was synthesized using mechanochemical alloying, and the influence of temperature (in the range of 600–750°C) on the decomposition of C−C alkanes into a carbon nanomaterial was investigated. The Ni−Sn system demonstrated a high carbon yield exceeding 300 g/g at T > 710°C. The calculated value of the apparent activation energy of reaction was 140 ± 5 kJ/mol. The effect of reaction temperature on the morphology, structure, and textural characteristics of produced carbon nanomaterial was explored. Regardless of the process temperature, the product consisted of nanofibers with thickness ranging from 5 to 100 nm. The obtained material exhibited a significant specific surface area (up to 450 m/g) and high pore volume (up to 0.80 cm/g).
Keywords
Ni−Sn-катализатор массивный сплав углеводороды C−C каталитический пиролиз углеродные нановолокна
Date of publication
01.04.2025
Year of publication
2025
Number of purchasers
0
Views
26

References

  1. 1. Хетагурова Э.О., Борзыкина Е.А. // Вестник науки. 2021. T. 5. № 5. C. 135.
  2. 2. The World Bank and Global Gas Flaring Reduction Partnership. 2024. Global Gas Flaring Tracker Report. https://thedocs.worldbank.org/en/doc/d01b4aebd8a10513c0e341de5e1f652e-0400072024/original/GlobalGas-Flaring-Tracker-Report-June-20-2024.pdf (Доступ 4 июня 2025 г.)
  3. 3. Gomes A.C.S., Shcherba V.A., Vorobyev K.A. Chekushina T.V. // Proceedings of the 5th International Conference on Construction, Architecture and Technosphere Safety. Sochi, Russia, 2022. V. 168. P. 442.
  4. 4. Арутюнов В.С. // Российский химический журнал. 2010. T. 54. № 5. C. 31.
  5. 5. Арутюнов В.С., Кирюшин А.А., Шмелев В.М., Синев М.Ю. // Газохимия. 2010. T. 11. № 1. C. 16.
  6. 6. Никитин А.В., Трошин К.Я., Беляев А.А., Арутюнов А.В., Кирюшин А.А., Арутюнов В.С. // НефтеГазоХимия. 2018. № 3. C. 23.
  7. 7. Palmer C., Bunyan E., Gelinas J., Gordon M. J., Metiu H., McFarland E.W. // Energy Fuels. 2020. V. 34. № 12. P. 16073.
  8. 8. Mc Connachie M., Konarova M., Smart S. // Int. J. Hydrogen Energy. 2023. V. 48. № 66. P. 25660.
  9. 9. Kundu R., Ramasubramanian V., Neeli S.T., Ramsurn H. // Energy Fuels. 2021. V. 35. № 16. P. 13523.
  10. 10. Petukhova E.S., Afonnikova S.D., Fedorov A.L., Argunova A.G., Sleptsov V.V., Potylitsyna A.R., Bauman Y.I., Mishakov I.V., Shubin Y.V., Vedyagin A.A. // Colloids Surf. A: Physicochem. Eng. Asp. 2024. V. 699. Art. 134682.
  11. 11. Zaitseva N.A., Goidin V.V., Molchanov V.V., Chesnokov V.V., Buyanov R.A., Utkin V.A. // Kinet. Catal. 2011. V. 52. № 5. P. 770.
  12. 12. Shen W., Cui J., Chen C., Zhang L., Sun D. // J. Colloid Interface Sci. 2024. V. 659. P. 364.
  13. 13. Ozerova A.M., Potylitsyna A.R., Bauman Y.I., Tayban E.S., Lipatnikova I.L., Nartova A.V., Vedyagin A.A., Mishakov I.V., Shubin Y.V., Netskina O.V. // Materials. 2022. V. 15. № 23. Art. 8414.
  14. 14. Мишаков И.В., Афонникова С.Д., Бауман Ю.И., Шубин Ю.В., Тренихин М.В., Серкова А.Н., Ведягин А.А. // Кинетика и катализ. 2022. T. 63. № 1. C. 110.
  15. 15. Чесноков В.В. // Кинетика и катализ. 2022. T. 63. № 1. C. 77.
  16. 16. Karimi S., Bibak F., Meshkani F., Rastegarpanah A., Deng J., Liu Y., Dai H. // Int. J. Hydrogen Energy. 2021. V. 46. № 39. P. 20435.
  17. 17. Cazana F., Afailal Z., Gonzalez-Martin M., Sanchez J.L., Latorre N., Romeo E., Arauzo J., Monzon A. // ChemEngineering. 2022. V. 6. № 4. Art. 47.
  18. 18. Zhu Q., Wang G., Liu J., Su L., Li C. // ACS Appl. Mater. Interfaces. 2017. V. 9. № 36. P. 30711.
  19. 19. Robbins J.P., Ezeonu L., Tang Z., Yang X., Koel B.E., Podkolzin S.G. // ChemCatChem. 2022. V. 14. № 6. P. 1.
  20. 20. Koskin A.P., Stepanenko S.A., Alekseeva M.V., Bulavchenko O.A., Gerasimov E.Y., Lysikov A.I., Yeletsky P.M., Kaichev V.V., Yakovlev V.A. // Chem. Eng. J. 2023. V. 476. Art. 146629.
  21. 21. Voss G. // Z. Anorg. Allg. Chem. 2004. V. 57. № 1. P. 34.
  22. 22. Shubin Y.V., Maksimova T.A., Popov A.A., Varygin A.D., Fedorenko A.D., Gerasimov E.Y., Mishakov I.V., Vedyagin A.A. // Appl. Catal. A: Gen. 2024. V. 670. Art. 119546.
  23. 23. Shivtsov D.M., Bauman Y.I., Mishakov I.V., Shubin Y.V., Vedyagin A.A. // Diam. Relat. Mater. 2025. V. 154. Art. 112172.
  24. 24. Eckert J., Holzer J., Krill III C., Johnson W. // J. Mater. Res.1992. V. 7. № 8. P. 1980.
  25. 25. Kim K., Sumiyama K., Suzuki K. // J. non-crystalline solids. 1994. V. 168. № 3. P. 232.
  26. 26. Cepeda-Sanchez N.M., Diaz-Guillen J.A., Maczka M., Amador U., Fuentes A.F. // J. Mater. Sci. 2017. V. 52. № 20. P. 11933.
  27. 27. Pithakratanayothin S., Tongsri R., Chaisuwan T., Wongkasemjit S. // Catal. Sci. Technol. 2017. V. 7. № 22. P. 5413.
  28. 28. Wang J., Jin L., Li Y., Wang M., Hu H. // Int. J. Hydrogen Energy. 2018. V. 43. № 37. P. 17611.
  29. 29. Zavarukhin S.G., Kuvshinov G.G. // Appl. Catal. A: Gen. 2004. V. 272. № 1–2. P. 219.
  30. 30. Brunauer S., Emmett P.H., Teller E. // J. Am. Chem. Soc. 2002. V. 60. № 2. P. 309.
  31. 31. Gor G.Y., Thommes M., Cychosz K.A., Neimark A.V. // Carbon. 2012. V. 50. № 4. P. 1583.
  32. 32. Wojdyr M. // J. Appl. Crystallography. 2010. V. 43. № 5. P. 1126.
  33. 33. Ferrari A.C., Robertson J. // Phys. Rev. B. 2000. V. 61. № 20. P. 14095.
  34. 34. Nash P., Nash A. // Bull. Alloy Phase Diagrams. 1985. V. 6. № 4. P. 350.
  35. 35. Tong S., Miao B., Zhang L., Chan S.H. // Energies. 2022. V. 15. № 7. Art. 2573.
  36. 36. Thommes M., Kaneko K., Neimark A.V., Olivier J.P., Rodriguez-Reinoso F., Rouquerol J., Sing K.S.W. // Pure Appl. Chem. 2015. V. 87. № 9–10. P. 1051.
  37. 37. Potylitsyna A.R., Bauman Y.I., Ayupov A.B., Plyusnin P.E., Shubin Y.V., Stoyanovskii V.O., Vedyagin A.A., Mel’gunov M.S., Korenev S.V., Mishakov I.V. // Diam. Relat. Mater. 2024. V. 148. Art. 114416.
  38. 38. Brubaker Z.E., Langford J.J., Kapsimalis R.J., Niedziela J.L. // J. Mater. Sci. 2021. V. 56. № 27. P. 15087.
  39. 39. Nemanich R.J., Solin S.A. // Phys. Rev. B. 1979. V. 20. № 2. P. 392.
  40. 40. Tuinstra F., Koenig J.L. // J. Chem. Phys. 1970. V. 53. № 3. P. 1126.
  41. 41. Moseenkov S.I., Kuznetsov V.L., Zolotarev N.A., Kolesov B.A., Prosvirin I.P., Ishchenko A.V., Zavorin A.V. // Materials. 2023. V. 16. № 3. Art. 1112.
QR
Translate

Indexing

Scopus

Scopus

Scopus

Crossref

Scopus

Higher Attestation Commission

At the Ministry of Education and Science of the Russian Federation

Scopus

Scientific Electronic Library