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RAS Chemistry & Material ScienceКинетика и катализ Kinetics and Catalysis

  • ISSN (Print) 0453-8811
  • ISSN (Online) 3034-5413

Bimetallic (Co, Fe, Ni)MgAlO layered double hydroxides based catalysts for the process of ammonia decomposition

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PII
S3034541325040048-1
DOI
10.7868/S3034541325040048
Publication type
Article
Status
Published
Authors
Z.A. Fedorova
  • Affiliation:
    Boreskov Institute of Catalysis SB RAS
    Institute of Solid State Chemistry and Mechanochemistry SB RAS
V.A. Borisov
  • Affiliation: New Chemical Technologies Center, Boreskov Institute of Catalysis SB RAS
B. Abbas
  • Affiliation: Novosibirsk State University
V.P. Pakharukova
  • Affiliation: Boreskov Institute of Catalysis SB RAS
E.Yu. Gerasimov
  • Affiliation: Boreskov Institute of Catalysis SB RAS
A.Yu. Gladkiy
  • Affiliation: Boreskov Institute of Catalysis SB RAS
D.A. Shlyapin
  • Affiliation: Boreskov Institute of Catalysis SB RAS
P.V. Snytnikov
  • Affiliation: Boreskov Institute of Catalysis SB RAS
Volume/ Edition
Volume 66 / Issue number 4
Pages
281-292
Abstract
In this work, monometallic MMgAlO and bimetallic MMMgAlO (M – Co,Fe, Ni) layered double hydroxides based catalysts were synthesized by the coprecipitation method. It was found that the samples dried at 110°C are layered double hydroxides with a hydrotalcite structure. After calcination at 550°C, the samples form mixed oxides with a specific nanostructure, intermediate between the NaCl and spinel type structures. The samples are characterized by a high specific surface area (105–209 m/g). The catalytic activity was studied in the ammonia decomposition process. Among all the catalysts, the CoNiMgAlO catalyst has the highest activity: at 550°C and GHSV 72000 mL h g ammonia conversion was 32%, which corresponds to H productivity of 25.7 mmol g min. According to the TEM, it was found that the average size of metal particles in the CoNiMgAlO catalyst is 10–14 nm. The CoNiMgAlO catalyst showed stable activity during the all testing period in the ammonia decomposition process (~40 h).
Keywords
биметаллические катализаторы разложение аммиака никелевые катализаторы никель-кобальтовые катализаторы слоистые двойные гидроксиды
Date of publication
01.04.2025
Year of publication
2025
Number of purchasers
0
Views
28

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