RAS Chemistry & Material ScienceКинетика и катализ Kinetics and Catalysis

  • ISSN (Print) 0453-8811
  • ISSN (Online) 3034-5413

Nitrogen-doped rice husk ash as a support for nickel catalysts for carbon dioxide hydrogenation to methane

PII
S3034541325060037-1
DOI
10.7868/S3034541325060037
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 66 / Issue number 6
Pages
513-526
Abstract
This work presents the synthesis of nickel catalysts for CO hydrogenation. The supports were prepared by thermal treatment of a mixture of rice husk, urea, and sodium bicarbonate at 500–700°С. The introduction of urea into the mixture promoted nitrogen doping of the support surface during calcination, affecting the textural and acid-base properties of the material. Nickel catalysts with a nominal metal content of 17% were synthesized by incipient wetness impregnation using a nickel(II) nitrate solution. One of the objectives of the study was to evaluate the effect of nitrogen doping on the dispersion and distribution of nickel particles. The prepared catalysts were tested in the CO methanation reaction, which allowed the relationship between the support preparation conditions and its catalytic activity to be determined. It has been shown that nickel catalysts for CO hydrogenation to methane can be synthesized using nitrogen-modified rice husk ash as a support.
Keywords
никелевые катализаторы гидрирование диоксид углерода метан рисовая шелуха азот
Date of publication
22.10.2025
Year of publication
2025
Number of purchasers
0
Views
47

References

  1. 1. Popova M., Dimitrov M., Oykova M., Shestakova P., Kovacheva D., Atanasova G., Szegedi Á. // Environ. Sci. Pollut. Res. 2025. P. 1. https://doi.org/10.1007/s11356-025-35931-5
  2. 2. Lv C., Xu L., Chen M., Cui Y., Wen X., Li Y., Wu C., Yang B., Miao Z., Hu X., Shou Q. // Front. Chem. 2020. V. 8. P. 269. https://doi.org/10.3389/fchem.2020.00269
  3. 3. Chen Y., Li H., Liu J., Liu N., Zhang Y., Guo Q., Wang F., Liu Q. // SSRN. 2022. V. 47. № 49. P. 21173. https://doi.org/10.1016/j.ijhydene.2022.04.249
  4. 4. Paviotti M.A., Faroldi B.M., Cornaglia L.M. // J. Environ. Chem. Eng. 2021. V. 9. № 3. Art. 105173. https://doi.org/10.1016/j.jece.2021.105173
  5. 5. Shen L., Xu J., Zhu M., Han Y.-F. // ACS Catal. 2020. V. 10. № 24. P. 14581. https://doi.org/10.1021/acscatal.0c03471
  6. 6. Zhu L., Yin Sh., Yin Q., Wang H., Wang Sh. // Energy Sci. Eng. 2015. V. 3. № 2. P. 126. https://doi.org/10.1002/ese3.58
  7. 7. Sevilla M., Valle-Vigón P., Fuertes A.B. // Adv. Funct. Mater. 2011. V. 21. № 14. P. 2781. https://doi.org/10.1002/adfm.201100291
  8. 8. Tang M., Deng J., Li M., Li X., Li H., Chen Zh., Wang Y. // Green Chem. 2016. V. 18. № 22. P. 6082. https://doi.org/10.1039/C6GC01858K
  9. 9. Cao Y., Mao S., Li M., Chen Y., Wang Y. // ACS Catal. 2017. V. 7. P. 8090. https://doi.org/10.1021/acscatal.7b02335
  10. 10. Thommes M., Kaneko K., Neimark A.V., Olivier J.P., Rodriguez-Reinoso F., Rouquerol J., Sing K.S.W. // Pure Appl. Chem. 2015. V. 87. № 9—10. P. 1051. https://doi.org/10.1515/pac-2014-1117
  11. 11. Chernyak S.A., Ivanov A.S., Arkhipova E.A., Shumyantsev A.V., Strokova N.E., Maslakov K.I., Savilov S.V., Lunin V.V. // Appl. Surf. Sci. 2019. V. 484. P. 228. https://doi.org/10.1016/j.apsusc.2019.04.077
  12. 12. Boehm H.-P. Ch. 7. Catalytic Properties of Nitrogen-Containing Carbons / In: Carbon Materials for Catalysis. Eds. P. Serp, J.L. Figueiredo. Wiley, 2008. P. 219. https://doi.org/10.1002/9780470403709.ch7
  13. 13. Dang T.A., Chau C.N. // JES. 1996. V. 143. P. 302. https://doi.org/10.1149/1.1836427
  14. 14. Watson C., Dikeman E. // Cereal Chem. 1977. V. 54. P. 120.
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