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RAS Chemistry & Material ScienceКинетика и катализ Kinetics and Catalysis

  • ISSN (Print) 0453-8811
  • ISSN (Online) 3034-5413

Composite photocatalysts CdZnS/TiO for hydrogen evolution from aqueous solutions of organic and inorganic sacrificial agents

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PII
S3034541325060061-1
DOI
10.7868/S3034541325060061
Publication type
Article
Status
Published
Authors
A.V. Zhurenok
  • Affiliation: Federal Research Center Boreskov Institute of Catalysis SB RAS
N. Bu
  • Affiliation:
    Novosibirsk National Research State University
    Heilongjiang University
D.D. Mishchenko
  • Affiliation:
    Federal Research Center Boreskov Institute of Catalysis SB RAS
    Multiaccess Center "SKIF" Boreskov Institute of Catalysis
E.Yu. Gerasimov
  • Affiliation: Federal Research Center Boreskov Institute of Catalysis SB RAS
E.A. Kozlova
  • Affiliation: Federal Research Center Boreskov Institute of Catalysis SB RAS
Volume/ Edition
Volume 66 / Issue number 6
Pages
557-570
Abstract
The photocatalytic activity of CdZnS (x = 0–1) and TiO/CdZnS composites in the reaction of hydrogen evolution under visible light irradiation (λ = 410 nm) was studied. In the system with an aqueous solution of CHOH used as a sacrificial agent, the maximum activity (1.6 mmol g h) was demonstrated by CdZnS. When using 0.1 M NaS/0.1 M NaSO as a sacrificial additive, the activity of all CdZnS photocatalysts significantly increased, reaching a maximum of 7.0 mmol g h in the presence of CdZnS. The deposition of 1% TiO on CdZnS by mixing in acetone made it possible to synthesize a highly effective composite with an activity of 8.3 mmol g h, which corresponds to the world level. A key result is confirmation of the high stability of this composite in both organic and inorganic environments, opening up prospects for its practical application in photocatalytic hydrogen evolution.
Keywords
диоксид титана твердые растворы сульфидов кадмия и цинка фотокаталитическая активность выделение водорода этанол сульфид натрия сульфит натрия
Date of publication
08.10.2025
Year of publication
2025
Number of purchasers
0
Views
29

References

  1. 1. Tsvetkov P., Samuseva P., Nikolaychuk L. // Energy Convers. Manag. 2024. V. 314. Art. 118671. https://doi.org/10.1016/j.enconman.2024.118671
  2. 2. Şen Z. // Prog. Energy Combust. Sci. 2004. V. 30. № 4. P. 367. https://doi.org/10.1016/j.pecs.2004.02.004
  3. 3. Козлова Е.А., Пармон В.Н. // Успехи химии. 2017. Т. 86. № 9. С. 870. https://doi.org/10.1070/RCR4739
  4. 4. Злотин С.Г., Егорова К.С., Анаников В.П., Акулов А.А., Вараксин М.В., Чупахин О.Н., Чарушин В.Н., Брыляков К.П., Аверин А.Д., Белецкая И.П., Доленговский Е.Л. // Успехи химии. 2023. Т. 92. № 12. RCR5104:1–187. https://doi.org/10.59761/rcr5104
  5. 5. Yusuf M., Rosha P., Qureshi F., Ali F.M., Ibrahim H. // Sustain. Mater. Technol. 2025. V. 43. Art. e01332. https://doi.org/10.1016/j.susmat.2025.e01332
  6. 6. Zou C., Li J., Zhang X., Jin X., Xiong B., Yu H., Liu X., Wang S., Li Y., Zhang L., Miao S. // Nat. Gas Ind. B. 2022. V. 9. № 5. P. 427. https://doi.org/10.1016/j.ngib.2022.04.006
  7. 7. Журенок А.В., Марковская Д.В., Потапенко К.О., Черепанова С.В., Сараев А.А., Герасимов Е.Ю., Козлова Е.А. // Кинетика и катализ. 2022. Т. 63. № 3. С. 248. https://doi.org/10.1134/S0023158422030107
  8. 8. Isa A.T., Hafeez H.Y., Mohammed J., Kafadi A.D.G., Ndikilar C.E., Suleiman A.B. // J. Alloy. Compd. Commun. 2024. V. 4. P. 100043. https://doi.org/10.1016/j.jacom.2024.10005
  9. 9. An S., Zhang L., Ding X., Xue Y., Tian J., Qin Y., You J., Wang X., Zhang H. // J. Colloid Interface Sci. 2024. V. 664. P. 848. https://doi.org/10.1016/j.jcis.2024.03.087
  10. 10. Zakariyya Y., Hafeez H.Y., Mohammed J., Ndikilar C.E., Suleiman A.B., Umaru D. // Int. J. Hydrogen Energy. 2024. V. 95. P. 185. https://doi.org/10.1016/j.ijhydene.2024.11.031
  11. 11. Borrell L., Cervera-March S., Giménez J., Simarro R., Andújar J.M. // Sol. Energy Mater. Sol. Cells. 1992. V. 25. № 1. P. 25. https://doi.org/10.1016/0927-0248 (92)90014-G
  12. 12. Moloto N., Moloto M.J., Kalenga M., Govindraju S., Airo M. // Opt. Mater. (Amst). 2013. V. 36. № 1. P. 31. https://doi.org/10.1016/j.optmat.2013.06.023
  13. 13. Zhong W., Huang X., Xu Y., Yu H. // Nanoscale. 2018. V. 10. № 41. P. 19418. https://doi.org/10.1039/c8nr06883f
  14. 14. Sun B., Wu J., Wang W., Wang H., Li Y., Guo Z., Geng Y., Lin H., Wang L. // Appl. Surf. Sci. 2021. V. 542. Art. 148542. https://doi.org/10.1016/j.apsusc.2020.148542
  15. 15. Hamdan S., Al-Ali K., Vega L.F., Muscetta M., Yusuf A.O., Palmisano G. // J. Environ. Chem. Eng. 2024. V. 12. № 5. Art. 113937. https://doi.org/10.1016/j.jece.2024.113937
  16. 16. Hu L., Liu X., Dai R., Lai H., Li J. // Fuel. 2025. V. 382. Art. 133737. https://doi.org/10.1016/j.fuel.2024.133737
  17. 17. Sushnikova A.A., Valeeva A.A., Zhurenok A.V., Sipatov I.S., Rempel A.A. // Kinet. Catal. 2024. V. 65. № 6. P. 710. https://doi.org/10.1134/S0023158424620389
  18. 18. Polevoi L.A., Kozlova E.A., Zhurenok A.V., Gerasimov E.Y., Saraev A.A., Golikova M.V., Baranchikov A.E. // Kinet. Catal. 2024. V. 65. № 5. P. 565. https://doi.org/10.1134/S0023158424601980
  19. 19. Алексеев Р.Ф., Сараев А.А., Куренкова А.Ю., Козлова Е.А. // Успехи химии. 2024. Т. 93. № 5. RCR5124: 1–23. https://doi.org/10.59761/RCR5124
  20. 20. Zhurenok A.V., Markovskaya D.V., Gerasimov E.Y., Cherepanova S.V., Bukhtiyarov A.V., Kozlova E.A. // RSC Adv. 2021. V. 11. № 60. P. 37966. https://doi.org/10.1039/d1ra06845h
  21. 21. Wang L., Geng X., Zhang L., Liu Z., Wang H., Bian Z. // Chemosphere. 2022. V. 286. Art. 131558. https://doi.org/10.1016/j.chemosphere.2021.131558
  22. 22. Pellegrin Y., Odobel F. // Comptes Rendus Chim. 2017. V. 20. № 3. P. 283. https://doi.org/10.1016/j.crci.2015.11.026
  23. 23. Potapenko K.O., Gerasimov E.Y., Cherepanova S.V., Saraev A.A., Kozlova E.A. // Materials (Basel). 2022. V. 15. № 22. P. 8026. https://doi.org/10.3390/ma15228026
  24. 24. Журенок А.В., Марковская Д.В., Потапенко К.О., Сидоренко Н.Д., Черепанова С.В., Сараев А.А., Герасимов Е.Ю., Козлова Е.А. // Кинетика и катализ. 2023. Т. 64. № 3. С. 250. https://doi.org/10.1134/S002315842030114
  25. 25. Tkachenko P., Volchek V., Kurenkova A., Gerasimov E., Popovetskiy P., Asanov I., Yushina I., Kozlova E., Vasilchenko D. // Int. J. Hydrogen Energy. 2022. V. 48. P. 1705. https://doi.org/10.1016/j.ijhydene.2022.11.265
  26. 26. Kurenkova A.Y., Medvedeva T.B., Gromov N.V., Bukhtiyarov A.V., Gerasimov E.Y., Cherepanova S.V., Kozlova E.A. // Catalysts. 2021. V. 11. № 7. P. 870. https://doi.org/10.3390/catal11070870
  27. 27. Potapenko K.O., Kurenkova A.Y., Bukhtiyarov A.V., Gerasimov E.Y., Cherepanova S.V., Kozlova E.A. // Nanomaterials. 2021. V. 11. № 2. P. 355. https://doi.org/10.3390/nano11020355
  28. 28. Любина Т.П., Козлова Е.А. // Кинетика и катализ. 2012. Т. 53. № 2. С. 188. https://doi.org/10.1134/S0023158412020061
  29. 29. Li C., Hu P., Meng H., Jiang Z. // J. Solution Chem. 2016. V. 45. P. 1. https://doi.org/10.1007/s10953-015-0422-1
  30. 30. Kurenkova A.Yu., Radina A.D., Baidyshev V.S., Povalyaev P.V., Aidakov E.E., Gerasimov E.Y., Mishchenko D.D., Zhurenok A.V., Pak A.Y., Kozlova E.A., Kvashnin A.G. // Appl. Surf. Sci. 2024. V. 661. Art. 160095. https://doi.org/10.1016/j.apsusc.2024.160095
  31. 31. Марковская Д.В., Люлюкин М.Н., Журенок А.В., Козлова Е.А. // Кинетика и катализ. 2021. Т. 62. № 4. С. 437.
  32. 32. Kovačič Ž., Likozar B., Huš M. // Fuel. 2022. V. 328. Art. 125322. https://doi.org/10.1016/j.fuel.2022.125322
  33. 33. Nagakawa H., Nagata M. // ACS Omega. 2021. V. 6. № 6. P. 4395. https://doi.org/10.1021/acsomega.0c05749
  34. 34. Li Q., Meng H., Zhou P., Zheng Y., Wang J., Yu J., Gong, J. // ACS Catal. 2013. V. 3. P. 882. https://doi.org/10.1021/cs4000975
  35. 35. Liu Y., Wang G., Li Y., Jin Z. // J. Colloid Interface Sci. 2019. V. 554. P. 113. https://doi.org/10.1016/j.jcis.2019.06.080
  36. 36. You D., Pan B., Jiang F., Zhou Y., Su W. // Appl. Surf. Sci. 2016. V. 363. P. 154. https://doi.org/10.1016/j.apsusc.2015.12.021
  37. 37. Shahzad A., Rafiq K., Abid M.Z., Shah H.U.R., Rauf A., Hussain E. // Appl. Catal. A: Gen. 2025. V. 693. Art. 120101. https://doi.org/10.1016/j.apcata.2025.120101
  38. 38. Sun H., Xiao Z., Zhao Z., Zhai S., An Q. // Appl. Surf. Sci. 2023. V. 611. Art. 155631. https://doi.org/10.1016/j.apsusc.2022.155631
  39. 39. Wenhua X., Hu X., Liu E., Fan J. // Appl. Surf. Sci. 2018. V. 447. P. 263. https://doi.org/10.1016/j.apsusc.2018.04.048
  40. 40. Islam A., Malek A., Islam M.T., Nipa F.Y., Raihan O., Mahmud H., Uddin M.E., Ibrahim M.L., Abdulkarreem-Alsultan G., Mondal A.H., Hasan M.M. et. al. // Int. J. Hydrogen Energy. 2025. V. 101. P. 173. https://doi.org/10.1016/j.ijhydene.2024.12.300
  41. 41. Patnaik S., Sahoo D.P., Parida K. // Carbon. 2021. V. 172. P. 682. https://doi.org/10.1016/j.carbon.2020.10.073
  42. 42. Kumaravel V., Imam M.D., Badreldin A., Chava R.K., Do J.Y., Kang M., Abdel-Wahab A. // Catalysts. 2019. V. 9. № 3. P. 276. https://doi.org/10.3390/catal9030276
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