Effect of the Nature of Alkali Metal on the Activity of Carbon Nanofibers in the Catalytic Decomposition of Formic Acid

Chesnokov, V. V.; Prosvirin, I. P.; Gerasimov, E. Yu.; Miliushina, A. S.

doi:10.7868/S3034541325030031

PII

S30345413S0453881125030031-1

DOI

10.7868/S3034541325030031

Publication type

Article

Status

Published

Authors

V. V. Chesnokov

Affiliation: Boreskov Institute of Catalysis SB RAS

I. P. Prosvirin

Affiliation: Boreskov Institute of Catalysis SB RAS

E. Yu. Gerasimov

Affiliation: Boreskov Institute of Catalysis SB RAS

A. S. Miliushina

Affiliation: Boreskov Institute of Catalysis SB RAS

Volume/ Edition

Volume 66 / Issue number 3

Pages

177-188

Abstract

The catalytic activity of carbon nanofibers modified by alkali metals in the reaction of formic acid decomposition has been studied. It was found that the catalytic activity increases in the sequence: 4% LiOH/CNF, 4% NaOH/CNF, 4% KOH/CNF, that is, the higher the basicity of the alkali metal, the higher the catalyst activity. The nature of the alkali metal has little effect on the selectivity in the reaction of formic acid decomposition on CNF. It is mainly the dehydrogenation reaction of formic acid with the formation of H and CO. In the case of KOH/CNF catalysts it is shown by a number of physical methods of investigation that alkaline treatment leads to modification of the CNF surface by potassium ions, which are uniformly distributed on the carbon surface in the form of functional groups; in addition, nanoparticles of potassium hydrogen carbonate are present at an increased content of applied potassium hydroxide.

Keywords

муравьиная кислота разложение углеродные нановолокна щелочная обработка гидроксид калия

Date of publication

01.03.2026

Year of publication

2026

Number of purchasers

Views

References

1. Gil-San-Millan R., Grau-Atienza A., Johnson D.T., Rico-Frances S., Serrano E., Linares N., García-Martínez J. // Int. J. Hydrogen Energy. 2018. V. 43. № 36. P. 17100.
2. Jiménez D.G., Delgado J.J., Lefferts L., Faria J., Calvino J.J., Cauqui M.Á. // Nanomaterials. 2019. V. 9. № 11. P. 1582.
3. Nielsen M., Alberico E., Baumann W., Drexler H.-J., Junge H., Gladiali S., Beller M. // Nature. 2013. V. 495. P. 85.
4. Капран А.Ю., Орлик С.Н. // Теоретическая и экспериментальная химия. 2017. Т. 53. № 1. С. 3.
5. Valera-Medina A., Xiao H., Owen-Jones M., David W.I.F., Bowen P.J. // Prog. Energy Combust. Sci. 2018. V. 69. P. 63.
6. Борисов В.A., Иост К.Н., Петрунин Д.A., Темерев В.Л., Муромцев И.В., Арбузов А.Б., Тренихин М.В., Гуляева Т.И., Смирнова Н.С., Шляпин Д.А., Цырульников П.Г. // Кинетика и катализ. 2019. Т. 60. № 3. С. 394.
7. He L., Liang B., Huang Y., Zhang T. // Natl. Sci. Rev. 2018. V. 5. P. 356.
8. Zhang A., Yao Q., Lu Z.H. // Acta Chim. Sin. 2021. V. 79. P. 885.
9. Taube M., Rippin D., Cresswell D.L., Knecht W., Gruenenfelder N. // Int. J. Hydrogen Energy. 1983. V. 8. № 3. P. 213.
10. Taube M., Rippin D., Knecht W., Hakimifard D., Milisavljevic B., Gruenenfelder N. // Int. J. Hydrogen Energy. 1985. V. 10. № 9. P. 595.
11. Andersson J., Grönkvist S. // Int. J. Hydrogen Energy. V. 44. № 23. P. 11901.
12. Muthukumar P., Kumar A., Afzal M., Bhogilla S., Sharma P., Parida A., Jana S., Kumar E.A., Pai R.K., Jain I.P. // Int. J. Hydrogen Energy. V. 48. № 85. P. 33223.
13. Usman M.R., Cresswell D.L. // Int. J. Green Energy. 2013. V. 10. № 2. P. 177.
14. Niermann M., Beckendorff A., Kaltschmitt M., Bonhoff K. // Int. J. Hydrogen Energy. 2019. V. 44. № 13. P. 6631.
15. Eppinger J., Huang K-W. // ACS Energy Lett. 2017. V. 2. P. 188.
16. Zhong H., Iguchi M., Chatterjee M., Himeda Y., Xu Q., Kawanami H. // Adv. Sustain. Syst. 2018. V. 2. P. 1700161.
17. Grasemann M., Laurenczy G. // Energy Environ. Sci. 2012. V. 5. P. 8171.
18. Bulushev D.A., Ross J.R.H. // ChemSusChem. 2018. V. 11. P. 821.
19. Navlani-Garcia M., Mori K., Salinas-Torres D., Kuwahara Y., Yamashita H. // Front. Mater. 2019. V. 6. P. 44.
20. Li S., Singh S., Dumesic J.A., Mavrikakis M. // Catal. Sci. Technol. 2019. V. 9. P. 2836.
21. Bulushev D.A., Sobolev V.I., Pirutko L.V., Starostina A.V., Asanov I.P., Modin E., Chuvilin A.L., Gupta N., Okotrub A.V., Bulusheva L.G. // Catalysts. 2019. V. 9. № 4. 376:1-13.
22. Solakidou M., Deligiannakis Y., Louloudi M. // Int. J. Hydrogen Energy. 2018. V. 43. № 46. P. 21386.
23. Tedsree K., Li T., Jones S., Chan C.W.A., Yu K.M.K., Bagot P.A.J., Marquis E.A., Smith G.D.W., Tsang Sh.Ch.E. // Nat. Nanotechnol. 2011. V. 6. P. 302.
24. Zhang J., Wang H., Zhao Q., Di L., Zhang X. // Int. J. Hydrogen Energy. 2020. V. 45. № 16. P. 9624.
25. Yurderi M., Bulut A., Zahmakiran M., Kaya M. // Appl. Catal. B: Environ. 2014. V. 160–161. P. 514.
26. Sobolev V., Asanov I., Koltunov K. // Energies. 2019. V. 12. P. 4198.
27. Tang C., Surkus A.-E., Chen F., Pohl M.-M., Agostini G., Schneider M., Junge H., Beller M. // Angew. Chem. Int. Ed. 2017. V. 56. P. 16616.
28. Fujitsuka H., Nakagawa K., Hanprerakriengkrai S., Nakagawa H., Tago T. // J. Chem. Eng. Jpn. 2019. V. 52. P. 423.
29. Bulushev D.A., Chuvilin A.L., Sobolev V.I., Stolyarova S.G., Shubin Y.V., Asanov I.P., Ishchenko A.V., Magnani G., Riccò M., Okotrub A.V., Bulusheva L.G. // J. Mater. Chem. A. 2017. V. 5. P. 10574.
30. Bing Q., Liu W., Yi W., Liu J.-Y. // J. Power Sources. 2019. V. 413. P. 399.
31. Balaraman E., Nandakumar A., Jaiswal G., Sahoo M.K. // Catal. Sci. Technol. 2017. V. 7. P. 3177.
32. Bide Y., Nabid M.R., Etemadi B. // Int. J. Hydrogen Energy. 2016. V. 41. P. 20147.
33. Kazakova M.A., Selyutin A.G., Ishchenko A.V., Lisitsyn A.S., Koltunov K.Yu., Sobolev V.I. // Int. J. Hydrogen Energy. 2020. V. 45. P. 19420.
34. Boehm H.P. // Carbon 2012. V. 50. P. 3154.
35. Khavryuchenko O., Frank B., Trunschke A., Hermann K., Schlögl R. // J. Phys. Chem. C. 2013. V. 117. P. 6225.
36. Chesnokov V.V., Prosvirin I.P., Gerasimov E.Y., Miliushina A.S. // Int. J. Hydrogen Energy. 2024. V. 57. P. 530.
37. Чесноков В.В. // Кинетика и катализ. 2022. Т. 63. № 1. С. 77.
38. Chesnokov V.V., Chichkan A.S. // Int. J. Hydrogen Energy. 2009. V. 34. № 7. P. 2979.
39. Чесноков В.В., Зайковский В.И., Буянов Р.А., Молчанов В.В., Плясова Л.М. // Кинетика и катализ. 1994. Т. 35. № 1. С. 146.
40. Буянов Р.А., Чесноков В.В. // Катализ в промышленности. 2006. № 2. C. 3.
41. Зайковский В.И., Чесноков В.В., Буянов Р.А. // Кинетика и катализ. 2006. Т. 47. № 4. С. 620.
42. Chesnokov V.V., Buyanov R.A. // Russ. Chem. Rev. 2000. V. 69. № 7. P. 623.
43. https://xpspeak.software.informer.com/4.1/
44. Shchukarev A.V., Korolkov D.V. // CEJC. 2004. V. 2. № 2. P. 347.

GOST	Chesnokov V., Gerasimov E., Miliushina A., Prosvirin I. Effect of the Nature of Alkali Metal on the Activity of Carbon Nanofibers in the Catalytic Decomposition of Formic Acid // Kinetics and Catalysis. – 2025. – V. 66. – Issue number 3 C. 177-188 . URL: https://kincatras.ru/s30345413s0453881125030031-1/?version_id=123420. DOI: 10.7868/S3034541325030031
MLA	Chesnokov, V. V, Gerasimov, E. Yu, Miliushina, A. S, Prosvirin, I. P "Effect of the Nature of Alkali Metal on the Activity of Carbon Nanofibers in the Catalytic Decomposition of Formic Acid." Kinetics and Catalysis. 66.3 (2025).:177-188. DOI: 10.7868/S3034541325030031
APA	Chesnokov V., Gerasimov E., Miliushina A., Prosvirin I. (2025). Effect of the Nature of Alkali Metal on the Activity of Carbon Nanofibers in the Catalytic Decomposition of Formic Acid. Kinetics and Catalysis. vol. 66, no. 3, pp.177-188 DOI: 10.7868/S3034541325030031

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