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RAS Chemistry & Material ScienceКинетика и катализ Kinetics and Catalysis

  • ISSN (Print) 0453-8811
  • ISSN (Online) 3034-5413

Model bimetallic Pd-Co/HOPG catalysts: Preparation and XPS/STM study

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PII
S30345413S0453881125010053-1
DOI
10.7868/S3034541325010053
Publication type
Article
Status
Published
Authors
M. A. Panafidin
  • Affiliation: Boreskov Institute of Catalysis
Volume/ Edition
Volume 66 / Issue number 1
Pages
48-62
Abstract
Regularities of formation of bimetallic Pd–Co nanoparticles supported on the highly oriented pyrolytic graphite (HOPG) have been studied by a combination of STM and XPS techniques. Cobalt deposition on monometallic Pd/HOPG sample was determined to lead to formation of the bimetallic Pdcore–Coshell nanoparticles which then transformed into alloyed Pd–Co nanoparticles with homogeneous metal distribution resulting from sample heating at 400—500°C in ultrahigh vacuum. Heating of the Pd–Co/HOPG catalysts at temperatures higher than 500°C in ultrahigh vacuum was revealed to result in sintering of the nanoparticles. Under carbon monoxide environment in a range of temperatures 25—250°C, adsorption-induced segregation of palladium atoms on the surface of the bimetallic nanoparticles was shown to take place, with latter having volcano-shape temperature dependence with a maximum at 200°C. It was established that bimetallic Pd–Co nanoparticles in the model catalysts were stable against sintering up to 250°C in CO atmosphere.
Keywords
биметаллические катализаторы ВОПГ РФЭС адсорбционно-индуцированная сегрегация СТМ<sub></sub>
Date of publication
21.11.2025
Year of publication
2025
Number of purchasers
0
Views
17

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