RAS Chemistry & Material ScienceКинетика и катализ Kinetics and Catalysis

  • ISSN (Print) 0453-8811
  • ISSN (Online) 3034-5413

Study of Deactivation of Mg-Containing Zeolite Catalyst in Propane Conversion into Olefinic Hydrocarbons

PII
S30345413S0453881125030023-1
DOI
10.7868/S3034541325030023
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 66 / Issue number 3
Pages
166-176
Abstract
The process of deactivation of magnesium-containing zeolite in three interregeneration cycles of operation during the conversion of propane into olefin hydrocarbons has been studied. The main factors leading to a decrease in the activity and selectivity of the catalyst have been identified. The distribution and state of active components in the catalytic system before and after the reaction, as well as after oxidative regeneration of the catalyst have been investigated. The nature and amount of carbon deposits formed on the catalyst under study during the reaction have been established, and their absence after its regeneration has been proven.
Keywords
пропан олефиновые углеводороды дезактивация катализатора продукты уплотнения кокс активность селективность
Date of publication
01.03.2026
Year of publication
2026
Number of purchasers
0
Views
24

References

  1. 1. Khalil Y.P. Propylene in Demand: Roadblocks and Opportunitie, 2015. Available online: https://insights.globalspec.com/article/473/propylene-in-demand-roadblocks-and-opportunities
  2. 2. Amghizar I., Vandewalle L.A., Van Geem K.M., Marin G.B. // Engineering. 2017. V. 3. P. 171.
  3. 3. Liu S., Zhang B., Liu G. // React. Chem. Eng. 2021. V. 6. № 1. P. 9.
  4. 4. Chen S., Chang X., Sun G., Zhang T., Xu Y., Wang Y., Pei C., Gong J. // Chem. Soc. Rev. 2021. V. 5. P. 3315.
  5. 5. Liu S., Zhang B., Liu G. // React. Chem. Eng. 2021. V. 6. № 1. P. 9.
  6. 6. Sattler J.J., Ruiz-Martinez J., Santillan-Jimenez E., Weckhuysen B.M. // Chem. Rev. 2014. V. 519. № 114. P. 10613.
  7. 7. Левин В.О., Потехин В.М., Кудимова М.В. // Нефтепереработка и нефтехимия. Научно-технические достижения и передовой опыт. 2017. Т. 4. С. 28.
  8. 8. Погосян Н.М., Погосян М.Д., Шаповалова О.В., Стрекова Л.Н. Тавадян Л.А., Арутюнов В.С. // Нефтегазохимия. 2016. Т. 2. С. 38.
  9. 9. Восмерикова Л.Н., Восмериков А.А., Степанов А.А., Восмериков А.В. // Нефтегазохимия. 2024. № 3–4. С. 65.
  10. 10. Vosmerikov A.A., Vosmerikova L.N., Barbashin Ya.E., Vosmerikov A.V. // J. Siberian Federal University. Chemistry. 2024. V. 17. № 3. P. 419.
  11. 11. Gong J. // Chem. Soc. Rev. 2021. V. 50. P. 3315.
  12. 12. Hu Z., Yang D., Wang Z., Yuan Z. // Chin. J. Catal. 2019. V. 40. P. 1233.
  13. 13. Carrero C.A., Schloegl R., Wachs I.E., Schomaecker R. // ACS Catal. 2014. V. 4. P. 3357.
  14. 14. Honeywell Successfully Commissions Second C3 Oleflex™ Unit for Zhejiang Satellite [электронный ресурс]. Сайт Honeywell, режим доступа: https://www.honeywell.com/en-s/newsroom/pressreleases/2019/09/honeywell-successfully-commissions-second-c3-oleflex-unit-for-zhejiang-satellite (дата обращения: 02.06.2021)
  15. 15. Sun M., Hu Z., Wang H., Suo Y., Yuan Z.-Y. // ACS Catal. 2023. V. 13. № 7. P. 4719.
  16. 16. Wang W., Yao S., Deng S., Wang Y., Qiu C., Mao C., Wang J.G. // Langmuir. 2021. V. 37. P. 12529.
  17. 17. Lian Z., Si C., Jan F., Zhi S., Li B. // ACS Catal. 2021. V. 11. P. 9279.
  18. 18. Wang H.-Z., Sun L.-L., Sui Z.-J., Zhu Y.-A., Ye G.-H., Chen D., Zhou X.-G., Yuan W.-K. // Ind. Eng. Chem. Res. 2018. V. 57. P. 8647.
  19. 19. Восмериков А.А., Восмерикова Л.Н., Восмериков А.В. // Известия высших учебных заведений. Серия: Химия и химическая технология. 2023. Т. 66. № 11. С. 42.
  20. 20. Kalantari N., Farzi A., Hamooni F., Delibas N., Tarjomannejad A., Niaei A., Salari D. // J. SolGel Sci. Technol. 2024. P. 1‒20.
  21. 21. He H., Anfeng Z., Limin R., Xiaowa N., Min L., Yi L., Chuan S., Hong Y., Chunshan S., Xinwen G. // Catal. Today. 2022. V. 252. Art. 117529.
QR
Translate

Indexing

Scopus

Scopus

Scopus

Crossref

Scopus

Higher Attestation Commission

At the Ministry of Education and Science of the Russian Federation

Scopus

Scientific Electronic Library