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RAS Chemistry & Material ScienceКинетика и катализ Kinetics and Catalysis

  • ISSN (Print) 0453-8811
  • ISSN (Online) 3034-5413

XPS Study of Differences in Stability of MWCNTS and N-MWCNTS as a Support for Model Silver Catalyst for Ethylene Epoxidation

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PII
S30345413S0453881125030048-1
DOI
10.7868/S3034541325030048
Publication type
Article
Status
Published
Authors
A.A. Ananina
  • Affiliation: Boreskov Institute of Catalysis SB RAS
A.V. Nartova
  • Affiliation: Boreskov Institute of Catalysis SB RAS
R.I. Kvon
  • Affiliation: Boreskov Institute of Catalysis SB RAS
A.M. Dmitrachkov
  • Affiliation: Boreskov Institute of Catalysis SB RAS
M.A. Kazakova
  • Affiliation: Boreskov Institute of Catalysis SB RAS
G.V. Golubtsov
  • Affiliation: Boreskov Institute of Catalysis SB RAS
V.I. Bukhtiyarov
  • Affiliation: Boreskov Institute of Catalysis SB RAS
Volume/ Edition
Volume 66 / Issue number 3
Pages
189-203
Abstract
The effect of preparation conditions on the stability of N-MWCNT samples prepared under oxygen-free conditions by the method of catalytic gas-phase decomposition of ethylene at 680°C on the FeCo/AlO catalyst in the presence of NH, with respect to atmospheric oxygen was studied by the XPS method. The analysis of the oxygen and nitrogen contents in the N-MWCNT composition, as well as the shape of the C1s XPS line after sample removal from the reactor in the air depending on the volume fraction of ammonia in the reaction mixture, as well as after treatment in nitric acid indicates that at low NH contents (2–4 vol. %) the incorporation of nitrogen into the structure of nanotubes leads to an increase in the structure ordering / a decrease in disorder, as a result, the oxygen content in these samples is minimal. Comparison of the supported catalysts Ag/MWCNT-0n and Ag/N-MWCNT-4n shows that the introduction of nitrogen during the support synthesis allows not only to decrease the oxygen content in carbon nanotubes, but also to increase the oxidation stability of both the support itself and the silver catalyst based on it.
Keywords
рентгеновская фотоэлектронная спектроскопия N–МУНТ многостенные углеродные наногрубки серебряные катализаторы
Date of publication
01.03.2026
Year of publication
2026
Number of purchasers
0
Views
25

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